Ambiphilic Al−Cu Bonding
In: Angewandte Chemie International Edition, Jg. 60 (2021), Heft 26, S. 14390-14393
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Zugriff:
Copper‐alumanyl complexes, [LCu‐Al(SiN Dipp )], where L=carbene=NHC iPr (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and Me2 CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO 2 implies an ambiphilicity in the Cu–Al interaction that is dependent on the identity of the carbene co‐ligand.
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Ambiphilic Al−Cu Bonding
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Autor/in / Beteiligte Person: | Liu, Han‐Ying ; Schwamm, Ryan J. ; Hill, Michael S. ; Mahon, Mary F. ; McMullin, Claire L. ; Rajabi, Nasir A. ; Royal Commission for the Exhibition of 1851 ; Engineering and Physical Sciences Research Council |
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Zeitschrift: | Angewandte Chemie International Edition, Jg. 60 (2021), Heft 26, S. 14390-14393 |
Veröffentlichung: | Wiley, 2021 |
Medientyp: | academicJournal |
ISSN: | 1433-7851 |
DOI: | 10.1002/anie.202104658 |
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