Octahedral Molybdenum Cluster-Based Single Crystals as Fabry–Pérot Microresonators
In: ISSN: 1528-7483, 2022
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academicJournal
Zugriff:
International audience ; Single crystals built up from octahedral Mo6 cluster units, with appropriate geometry and size, constitute Fabry–Pérot-type optical microcavities with well-defined resonances. Such resonances appear in the VIS-NIR range when performing optical transmittance (OT) or photoluminescence (PL) measurements. They strongly depend on the crystal thickness and on the optical constants of the material, specifically the real and imaginary parts of the refractive index. In this work, the accurate measurement of the crystal thickness is used for the determination of the optical constants by means of a fitting process, and the preferred orientation of the crystals was determined by X-ray diffraction. © 2021 American Chemical Society
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Octahedral Molybdenum Cluster-Based Single Crystals as Fabry–Pérot Microresonators
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Autor/in / Beteiligte Person: | Segura-Sanchis, E. ; Fenollosa, R. ; Rodriguez, I. ; Molard, Y. ; Cordier, Stéphane ; Feliz, M. ; Atienzar, P. ; Universitat Politècnica de València = Universitad Politecnica de Valencia = Polytechnic University of Valencia (UPV) ; Synthèse Caractérisation Analyse de la Matière (ScanMAT) ; Université de Rennes (UR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) ; Institut des Sciences Chimiques de Rennes (ISCR) ; Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes) ; Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) ; PGC2018-099744 ; SEV-2016-0683 ; Generalitat Valenciana, GVA: AICO/2020/149 |
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Zeitschrift: | ISSN: 1528-7483, 2022 |
Veröffentlichung: | HAL CCSD ; American Chemical Society, 2022 |
Medientyp: | academicJournal |
DOI: | 10.1021/acs.cgd.1c01144 |
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