Electron scavenging by COS in the radiolysis of supercritical cis - and trans -2- butene
In: Canadian Journal of Chemistry, Jg. 55 (1977), Heft 22, S. 3933-3935
academicJournal
Zugriff:
The electron scavenging reaction with COS was studied in γ-irradiated supercritical butenes in the density range 0.24–0.48 g/cm 3 at 170 ± 1°C and in the liquid phase at room temperature. G(CO) fi estimated by means of the 'square root' model at each density studied agreed within experimental accuracy with G(N 2 ) fi obtained previously. In liquid butenes, G(CO) fi , as well as G(N 2 ) fi , agreed with G fi obtained by electrical measurements. Rate constants estimated from the reactivity parameters for reactions with COS were less than 1/10 of those with N 2 O at each density studied except at d = 0.48 g/cm 3 in trans-2-butene.
| Titel: |
Electron scavenging by COS in the radiolysis of supercritical cis - and trans -2- butene
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| Autor/in / Beteiligte Person: | Nishikawa, Masaru ; Imai, Kazuo ; Soma, Yuko |
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| Zeitschrift: | Canadian Journal of Chemistry, Jg. 55 (1977), Heft 22, S. 3933-3935 |
| Veröffentlichung: | Canadian Science Publishing, 1977 |
| Medientyp: | academicJournal |
| ISSN: | 0008-4042 |
| DOI: | 10.1139/v77-557 |
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