Role of bridging ligand .pi.-acidity in determining the nature of the lowest excited states of binuclear complexes of nickel(0). Ligand-centered (M2 .fwdarw. .mu.-LCT), metal-centered (.mu.-L .fwdarw. M2CT), and intraligand (IL) lowest excited states for the series of complexes Ni2(.mu.-L)(CNMe)2(PPh2CH2PPh2)2 (L = CNR, CNMe(R)+, NO+)
In: Inorganic Chemistry, Jg. 29 (1990), Heft 20, S. 4022-4027
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Role of bridging ligand .pi.-acidity in determining the nature of the lowest excited states of binuclear complexes of nickel(0). Ligand-centered (M2 .fwdarw. .mu.-LCT), metal-centered (.mu.-L .fwdarw. M2CT), and intraligand (IL) lowest excited states for the series of complexes Ni2(.mu.-L)(CNMe)2(PPh2CH2PPh2)2 (L = CNR, CNMe(R)+, NO+)
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Autor/in / Beteiligte Person: | Ratliff, K. S. ; DeLaet, D. L. ; Gao, J. ; Fanwick, P. E. ; Kubiak, C. P. |
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Zeitschrift: | Inorganic Chemistry, Jg. 29 (1990), Heft 20, S. 4022-4027 |
Veröffentlichung: | American Chemical Society (ACS), 1990 |
Medientyp: | academicJournal |
ISSN: | 0020-1669 |
DOI: | 10.1021/ic00345a023 |
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