Controlling the Reactivity of IBA‐N 3 by Switching Halogen Salts: Providing a Universal Strategy for Haloazidation of Alkenes
In: Chinese Journal of Chemistry ; ISSN 1001-604X 1614-7065, 2024
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Zugriff:
Comprehensive Summary Although various routes have been reported for haloazidation, unavoidable problems exist, such as environmentally unfriendly monomer halogen, the need for in situ generation of unstable halogen azides (XN 3 ), applicability to one type of haloazidation and inability to precisely control selectivity. Herein, we developed a universal strategy for haloazidation of alkenes through controlling the reactivity of IBA‐N 3 by switching halogen salts, allowing for the synthesis of a diversity of halogen azide products. Mechanistic studies have shown that by tuning the reactivity of IBA‐N 3 via switching halogen salts, different intermediates can be controllably produced to achieve regioselectivity and chemoselectivity in the haloazidation of alkenes.
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Controlling the Reactivity of IBA‐N 3 by Switching Halogen Salts: Providing a Universal Strategy for Haloazidation of Alkenes
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Autor/in / Beteiligte Person: | Xia, Chen‐Xi ; Sun, Xin‐Lei ; Zhang, Jinfeng ; Ren, Yue ; Yu, Yan ; Wang, Kuai ; Meng, Ling‐Guo ; National Natural Science Foundation of China |
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Zeitschrift: | Chinese Journal of Chemistry ; ISSN 1001-604X 1614-7065, 2024 |
Veröffentlichung: | Wiley, 2024 |
Medientyp: | academicJournal |
DOI: | 10.1002/cjoc.202400108 |
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