Rhenium(I)-Catalyzed C‑Methylation of Ketones, Indoles, and Arylacetonitriles Using Methanol
2021
unknown
Zugriff:
A ReCl(CO) 5 /MeC(CH 2 PPh 2 ) 3 ( L2 ) system was developed for the C-methylation reactions utilizing methanol and base, following the borrowing hydrogen strategy. Diverse ketones, indoles, and arylacetonitriles underwent mono- and dimethylation selectively up to 99% yield. Remarkably, tandem multiple methylations were also achieved by employing this catalytic system.
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Rhenium(I)-Catalyzed C‑Methylation of Ketones, Indoles, and Arylacetonitriles Using Methanol
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Autor/in / Beteiligte Person: | Sujan Shee (4390537) ; Sabuj Kundu (1787752) |
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Veröffentlichung: | 2021 |
Medientyp: | unknown |
DOI: | 10.1021/acs.joc.1c00376.s002 |
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