The effect of sodium thiosulfate on cytotoxicity of a diimine Re(i) tricarbonyl complexElectronic supplementary information (ESI) available: Physical measurements and methods (NMR, FT-IR, ESI-MS, TG); crystal data, selected bond distances and bond angles for the compounds {Na(fac-[Re(CO)3(bpy)(S2O3)])·1.75H2O·C2H5OH}4 (2·0.75H2O·C2H5OH)4 and (fac-[Re(CO)3(bpy)(H2O)]) (fac-[Re(CO)3(bpy)(S2O3)])·4H2O (3); survey of Re(CO)3+ complexes with an S-donor ligand in the Cambridge Structural Database (CSD); 13C, 1H NMR and FT-IR spectra of 1 and 2; TG analysis, ESI-mass spectra and peak assignments for compound 2; XFM elemental distribution map and XFM spectra of MDA-MB-231 cells treated with 1, 2 or DMEM for 6 h. CCDC 2054796 and 2054797. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d1dt00517k

The effect of sodium thiosulfate on cytotoxicity of a diimine Re(i) tricarbonyl complexElectronic supplementary information (ESI) available: Physical measurements and methods (NMR, FT-IR, ESI-MS, TG); crystal data, selected bond distances and bond angles for the compounds {Na(fac-[Re(CO)3(bpy)(S2O3)])·1.75H2O·C2H5OH}4 (2·0.75H2O·C2H5OH)4 and (fac-[Re(CO)3(bpy)(H2O)]) (fac-[Re(CO)3(bpy)(S2O3)])·4H2O (3); survey of Re(CO)3+ complexes with an S-donor ligand in the Cambridge Structural Database (CSD); 13C, 1H NMR and FT-IR spectra of 1 and 2; TG analysis, ESI-mass spectra and peak assignments for compound 2; XFM elemental distribution map and XFM spectra of MDA-MB-231 cells treated with 1, 2 or DMEM for 6 h. CCDC 2054796 and 2054797. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d1dt00517k