Thermodynamic and kinetic studies on the complexation reactions of aqua(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) (blue) with neutral monodentate ligands
In: Journal of the Chemical Society. Dalton transactions, 1991, Heft 7, S. 1685-1689
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Zugriff:
In order to study the charge effects of the entering and leaving groups in substitution reactions of five-co-ordinate complexes, the equilibrium constants of the complexation reactions of a trigonal-bipyramidal complex, aqua(rac-hexamethyl-1,4,8,11-tetraazacyclotetradecane)- copper(II), [CuL(H2O)]2+ (blue isomer), with eight neutral monodentate ligands (L'), ammonia, methyl-, dimethyl-, trimethyl- and ethyl-amine, aniline, pyridine and piperidine, as well as the rate constants for the formation and the aquation of [CuL(L')]2+ have been determined.
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Thermodynamic and kinetic studies on the complexation reactions of aqua(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) (blue) with neutral monodentate ligands
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Autor/in / Beteiligte Person: | CHI-CHANG, CHANG ; CHUNG-SUN, CHUNG |
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Zeitschrift: | Journal of the Chemical Society. Dalton transactions, 1991, Heft 7, S. 1685-1689 |
Veröffentlichung: | Cambridge: Royal Society of Chemistry, 1991 |
Medientyp: | academicJournal |
Umfang: | print, 15 ref |
ISSN: | 0300-9246 (print) |
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