Sulfide Nanocrystal Inks for Dense Cu(ln1-xGax)(S1-ySey)2 Absorber Films and Their Photovoltaic Performance
In: Nano letters (Print), Jg. 9 (2009), Heft 8, S. 3060-3065
academicJournal
- print, 29 ref
Zugriff:
Recent developments in the colloidal synthesis of high quality nanocrystals have opened up new routes for the fabrication of low-cost efticien photovoltaic devices. Previously, we demonstrated the utility of CulnSe2 nanocrystals in the fabrication of Culnse2 thin film solar cells. In those devices, sintering the nanocrystal film yields a relatively dense CuinSe2 film with some void space inclusions. Here, we present a general approach toward eliminating void space in sintered nanocrystal films by utilizing reactions that yield a controlled volume expansion of the film. This is demonstrated by first synthesizing a nanocrystal ink composed of Cu(In1-xGax)S2 (CIGS). After nanocrystal film formation the nanocrystals are exposed to selenium vapor during which most of the suflur is replaced by selenium. Full replacement produces ~14.6% volume expansion and reproducibly leads to good dense device-quality CIGSSe absorber films with reduced inclusion of void space Solar cells made using the CIGSSe absorber films fabricated by this method showed a power conversion efficiency of 4.76% (5.55% based or the active nonshadowed area) under standard AM1.5 illumination.
Titel: |
Sulfide Nanocrystal Inks for Dense Cu(ln1-xGax)(S1-ySey)2 Absorber Films and Their Photovoltaic Performance
|
---|---|
Autor/in / Beteiligte Person: | QIJIE, GUO ; FORD, Grayson M ; HILLHOUSE, Hugh W ; AGRAWAL, Rakesh |
Link: | |
Zeitschrift: | Nano letters (Print), Jg. 9 (2009), Heft 8, S. 3060-3065 |
Veröffentlichung: | Washington, DC: American Chemical Society, 2009 |
Medientyp: | academicJournal |
Umfang: | print, 29 ref |
ISSN: | 1530-6984 (print) |
Schlagwort: |
|
Sonstiges: |
|