Multi-dimensional steric effect for XeI* (B) formation in the oriented Xe* (3P2, MJ = 2) + oriented CH3I reaction
In: PCCP. Physical chemistry chemical physics (Print), Jg. 12 (2010), Heft 26, S. 6949-6955
Online
academicJournal
- print, 37 ref
Zugriff:
Multi-dimensional steric effect for the XeI* (B) formation in the oriented Xe* (3P2, MJ = 2) + oriented CH3I reaction has been observed as a function of the mutual configuration between the molecular orientation and the atomic alignment in the collision frame. The molecular steric opacity function has been determined as a function of the atomic orbital alignment. The large molecular orientation dependence (i.e., the largest reactivity at the I-end and the large difference in the reaction probability between the I-end and the CH3-end) and the large molecular alignment dependence (the poor reactivity at the sideway) is recognized for each atomic orbital alignment. In addition, a clear correlation between the molecular orientation and the atomic orbital alignment is recognized (i.e., the Lz' = 0 atomic orbital alignment is favorable for the molecular axis direction, while the |Lz'| = I atomic orbital alignment is favorable for the sideway direction).
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Multi-dimensional steric effect for XeI* (B) formation in the oriented Xe* (3P2, MJ = 2) + oriented CH3I reaction
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Autor/in / Beteiligte Person: | OHOYAMA, H ; KASAI, T |
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Zeitschrift: | PCCP. Physical chemistry chemical physics (Print), Jg. 12 (2010), Heft 26, S. 6949-6955 |
Veröffentlichung: | Cambridge: Royal Society of Chemistry, 2010 |
Medientyp: | academicJournal |
Umfang: | print, 37 ref |
ISSN: | 1463-9076 (print) |
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