Effect of Ni cations and microwave hydrothermal treatment on the related properties of layered double hydroxide-ethylene vinyl acetate copolymer composites
In: Journal of colloid and interface science, Jg. 356 (2011), Heft 2, S. 519-525
academicJournal
- print, 59 ref
Zugriff:
The effect of Ni cations and synthetic methods on the crystallinity, morphology, thermal stability and hydrophobic properties of carbonate-containing layered double hydroxides (LDHs) was investigated. The conventional hydrothermal treatment (CHT) and microwave hydrothermal treatment (MHT) methods were used to synthesize LDHs. The microwave treatment LDHs (MgAl-MHT and NiMgAl-MHT) have higher crystallinity and smaller crystal sizes than the conventional hydrothermal treatment LDHs (MgAl-CHT and NiMgAl-CHT). IR results indicate that the interactions of both OH--CO23 and CO2-3 -CO2-3 in NiMgAl-MHT are weaker. Furthermore, the thermal decomposition of OH- and CO2-3 in the NiMgAl-MHT sample occurred earlier and faster than that of other LDHs. The contact angle values indicate that NiMgAl-MHT has the highest hydrophobicity. The influences of the LDHs on the thermal degradation and flame retardance of ethylene vinyl acetate copolymer (EVA)-LDH composites have also been studied in detail. NiMgAl-MHT has the more homogeneous nano-dispersed layers in EVA matrix. All composites enhance the thermal stability compared with the pure EVA because of the release of H2O and CO2. Flame retardance of NiMgAl-MHT-EVA was obviously higher than that of the pure EVA and other composites.
Titel: |
Effect of Ni cations and microwave hydrothermal treatment on the related properties of layered double hydroxide-ethylene vinyl acetate copolymer composites
|
---|---|
Autor/in / Beteiligte Person: | LILI, WANG ; BIN, LI ; MINGFEI, YANG ; CHUNXIA, CHEN ; YONGSHENG, LIU |
Link: | |
Zeitschrift: | Journal of colloid and interface science, Jg. 356 (2011), Heft 2, S. 519-525 |
Veröffentlichung: | Amsterdam: Elsevier, 2011 |
Medientyp: | academicJournal |
Umfang: | print, 59 ref |
ISSN: | 0021-9797 (print) |
Schlagwort: |
|
Sonstiges: |
|