Magnetic properties, phase evolution, and microstructure of melt spun Sm(Co1―zZrz)xCy (x = 5―9; y = 0―0.15; z = 0.03 and 0.06) ribbons
In: Journal of magnetism and magnetic materials, Jg. 324 (2012), Heft 6, S. 1006-1010
academicJournal
- print, 18 ref
Zugriff:
Magnetic properties, phase evolution, and microstructure of melt spun Zr-substituted Sm(Co1―zZrz)xCy (x = 5―9; y=0-0.15; z=0.03 and 0.06) ribbons quenched at the wheel speed of 40 m/s have been studied. The x-ray diffraction analysis showed that the main phases, found in Sm(Co0.97Zr0.03)x ribbons, were 1:5 phase for x = 5―5.5; 1:5 and 1:7 phases for x=6; 1:7 phase for x=6.5-7.5; 1:7 and 2:17 phases for x = 8; and only 2:17 phase for x = 8.5―9, respectively. For Sm(Co0.97Zr0.03)x ribbons, the attractive magnetic properties of remanent magnetization (Br) of 5.5 kG, intrinsic coercivity (iHc) of 9.5 kOe, and energy product ((BH)max) of 7.0 MGOe were obtained for Sm(CO0.97Zr0.03)6.5 ribbons. Furthermore, a slight amount of C addition in Sm(Co0.97Zr0.03)x ribbons could not only effectively refine the grain size from 200 to 500 nm for C-free ribbon to 10-70 nm for C-added ribbons, but also bring extremely fine fcc-Co grains (2-10 nm), leading to the strengthened exchange coupling effect between the magnetic grains. As a result, magnetic properties were further improved. In this study, the optimal magnetic properties of Br = 6.3 kG, iHc = 10.5 kOe, and (BH)max = 9.0 MGOe were achieved for Sm(Co0.97Zr0.03)7C0.1 nanocomposites.
Titel: |
Magnetic properties, phase evolution, and microstructure of melt spun Sm(Co1―zZrz)xCy (x = 5―9; y = 0―0.15; z = 0.03 and 0.06) ribbons
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Autor/in / Beteiligte Person: | CHANG, H. W ; GUO, C. S ; HSIEH, C. C ; CHANG, W. C |
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Zeitschrift: | Journal of magnetism and magnetic materials, Jg. 324 (2012), Heft 6, S. 1006-1010 |
Veröffentlichung: | Amsterdam: Elsevier, 2012 |
Medientyp: | academicJournal |
Umfang: | print, 18 ref |
ISSN: | 0304-8853 (print) |
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