Einzeltreffer — DigiBib

A new tris (aminomethyl) phosphine derived from N-methyl-2-phenylethanamine P(CH2N(CH3) CH2CH2Ph)3 (1) has been synthesized and characterized by the NMR spectra. Also, three new copper (I) iodide or isothiocyanate complexes with 1 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline (dmp) [CuI(phen)P(CH2N(CH3)CH2CH2Ph)3] (1P) CuI(dmp)P(CH2N(CH3)CH2CH2Ph)3] (11) and [CuNCS(dmp)P(CH2N(CH3)CH2CH2Ph)3] (1T), have been synthesized and characterized by elemental analysis as well as studied by NMR, UV-vis, IR and luminescence spectroscopies. An X-ray structure of 1P complex revealed that the geometry around Cu(l) center in this complex is distorted pseudo-tetrahedral. Investigated complexes exhibit orange, rather weak photoluminescence in the solid state. This relatively low intensity may be related to the high flattening deformations of the molecular geometries in the excited triplet states On the basis of TDDFT calculations we confirmed that the absorbance and luminescence bands of (MX,MPR3)LCT as well as of (MX)LCT types result mainly from the transitions from the copper-iodine (or isothiocyanate) bonds and a small admixture of copper-phosphine bonds to antibonding orbitals of phen or dmp diimines.

Titel:	Solid state luminescence of Cul and CuNCS complexes with phenanthrolines and a new tris (aminomethyl) phosphine derived from N-methyl-2-phenylethanamine
Autor/in / Beteiligte Person:	STAROSTA, Radosław ; KOMARNICKA, Urszula K ; PUCHALSKA, Małgorzata
Link:	E-Journal im Bestand der UB Hagen? View record from PASCAL Archive
Zeitschrift:	Journal of luminescence, Jg. 145 (2014), S. 430-437
Veröffentlichung:	Amsterdam: Elsevier, 2014
Medientyp:	academicJournal
Umfang:	print, 62 ref
ISSN:	0022-2313 (print)
Schlagwort:	Atomic molecular physics Physique atomique et moléculaire Condensed state physics Physique de l'état condensé Sciences exactes et technologie Exact sciences and technology Physique Physics Etat condense: structure, proprietes mecaniques et thermiques Condensed matter: structure, mechanical and thermal properties Structure des liquides et des solides; cristallographie Structure of solids and liquids; crystallography Structure de solides cristallins particuliers Structure of specific crystalline solids Etat condense: structure electronique, proprietes electriques, magnetiques et optiques Condensed matter: electronic structure, electrical, magnetic, and optical properties Résonances et relaxations magnétiques dans l'état condensé, effet mössbauer Magnetic resonances and relaxations in condensed matter, mössbauer effect Résonance et relaxation magnétiques nucléaires Nuclear magnetic resonance and relaxation Propriétés optiques, spectroscopie et autres interactions de la matière condensée avec les particules et le rayonnement Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Photoluminescence Complexe de cuivre Copper complexes Cuivre Copper Diffraction RX XRD Etat excité Excited states Etat solide Solid state Estado sólido Etat triplet Triplet state Iode Iodine Iodure de cuivre Copper iodide Cobre ioduro Luminescence Méthode fonctionnelle densité Density functional method Orbitale liaison Bond orbital Orbital enlace Phénanthroline Phenanthrolines Rayonnement UV Ultraviolet radiation Résonance magnétique nucléaire Nuclear magnetic resonance Spectre IR Infrared spectra Spectre RMN NMR spectra Structure cristalline Crystal structure Structure moléculaire Molecular structure I Phénanthroline dérivé Copper(I) complexes DFT calculations N-methyl-2-phenylethanamine Tris (aminomethyl) phosphine
Sonstiges:	Nachgewiesen in: PASCAL Archive Sprachen: English Original Material: INIST-CNRS Document Type: Article File Description: text Language: English Author Affiliations: Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland Rights: Copyright 2015 INIST-CNRS ; CC BY 4.0 ; Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS Notes: Physics of condensed state: electronic structure, electrical, magnetic and optical properties ; Physics of condensed state: structure, mechanical and thermal properties

Klicken Sie ein Format an und speichern Sie dann die Daten oder geben Sie eine Empfänger-Adresse ein und lassen Sie sich per Email zusenden.

BibTeX Citavi, JabRef, u.a.
(Literaturverwaltung)

PDF kein Volltext!
(Merkzettel, Notizen)

RIS Endnote, Citavi u.a.
(Literaturverwaltung)

MODS
(XML zur Weiterverarbeitung)

oder

Wählen Sie das für Sie passende Zitationsformat und kopieren Sie es dann in die Zwischenablage, lassen es sich per Mail zusenden oder speichern es als PDF-Datei.

Gewünschter Zitations-Stil:

oder

Bitte prüfen Sie, ob die Zitation formal korrekt ist, bevor Sie sie in einer Arbeit verwenden. Benutzen Sie gegebenenfalls den "Exportieren"-Dialog, wenn Sie ein Literaturverwaltungsprogramm verwenden und die Zitat-Angaben selbst formatieren wollen.

Solid state luminescence of Cul and CuNCS complexes with phenanthrolines and a new tris (aminomethyl) phosphine derived from N-methyl-2-phenylethanamine