Hydrogen production by steam reforming of simulated liquefied natural gas (LNG) over nickel catalyst supported on mesoporous phosphorus-modified alumina xerogel
In: Applied catalysis. B, Environmental, Jg. 148-149 (2014), S. 269-280
academicJournal
- print, 44 ref
Zugriff:
A series of nickel catalysts supported on mesoporous phosphorus-modified alumina xerogel (Ni/XPA, X = P/Al molar ratio) were prepared by an epoxide-driven sol―gel method and a subsequent incipient impregnation method, and they were applied to the hydrogen production by steam reforming of simulated liquefied natural gas (LNG). All the calcined phosphorus-modified alumina xerogel supports (XPA, X = P/Al molar ratio) retained a mesoporous structure with amorphous crystalline phase. The amount of penta-coordinated aluminum species increased with increasing X (P/Al molar ratio) of XPA supports. Although the calcined Ni/XPA catalysts retained both nickel oxide phase and nickel aluminate phase, relative distribution of nickel species of the catalysts was different depending on X (P/Al molar ratio). Among the catalysts, Ni/0.05PA catalyst showed the highest binding energy of nickel species. Crystallite size of metallic nickel increased with increasing X (P/Al molar ratio) in the reduced Ni/XPA catalysts. However, Ni/0.05PA catalyst showed the largest amount of strong hydrogen-binding sites and exhibited the largest amount of adsorbed methane in the H2-TPD and CH4-TPD measurements, respectively. Catalytic performance in the steam reforming of LNG over Ni/XPA catalysts showed a volcano-shaped trend with respect to X (P/Al molar ratio). This result was well correlated with the amount of adsorbed methane calculated from CH4-TPD measurements. Among the catalysts tested, Ni/0.05PA catalyst with the highest affinity toward methane showed the best catalytic performance in hydrogen production by steam reforming of LNG.
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Hydrogen production by steam reforming of simulated liquefied natural gas (LNG) over nickel catalyst supported on mesoporous phosphorus-modified alumina xerogel
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Autor/in / Beteiligte Person: | YONGJU, BANG ; SEUNG JU, HAN ; JAEKYEONG, YOO ; JUNG HO, CHOI ; JONG KWON, LEE ; JI HWAN, SONG ; JINWON, LEE ; IN KYU, SONG |
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Zeitschrift: | Applied catalysis. B, Environmental, Jg. 148-149 (2014), S. 269-280 |
Veröffentlichung: | Kidlington: Elsevier, 2014 |
Medientyp: | academicJournal |
Umfang: | print, 44 ref |
ISSN: | 0926-3373 (print) |
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