Monocyclooctatetraene uranium thiolate complexes. Crystal structure of [{U(η-C8H8)(μ-SPri)2}2]
In: Journal of the Chemical Society. Dalton transactions, 1994, Heft 4, S. 501-504
Online
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Zugriff:
The monocyclooctatetraene uranium bis(thiolate) complexes [U(cot)(SR)2] (cot=η-C8H8, R=Bun or Pri) were prepared by treating [U(cot)(BH4)2] 1 with the corresponding thiol or NaSR reagent. The isopropane thiolate derivative is a dimer in the crystalline form, with four bridging SPri ligands, and this structure is retained in solution. Reaction of 1 with NaSBut afforded the anion [U(cot)(SBut)3]- which adopts a three-legged piano-stool configuration.
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Monocyclooctatetraene uranium thiolate complexes. Crystal structure of [{U(η-C8H8)(μ-SPri)2}2]
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Autor/in / Beteiligte Person: | LEVERD, P. C ; ARLIGUIE, T ; LANCE, M ; NIERLICH, M ; VIGNER, J ; EPHRITIKHINE, M |
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Zeitschrift: | Journal of the Chemical Society. Dalton transactions, 1994, Heft 4, S. 501-504 |
Veröffentlichung: | Cambridge: Royal Society of Chemistry, 1994 |
Medientyp: | academicJournal |
Umfang: | print, 20 ref |
ISSN: | 0300-9246 (print) |
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