Synthesis and structural characterization of an unusual η3-ligated 1,3-diphosphacyclobutadiene molybdenum complex via cyclodimerization of a phosphaalkyne. Crystal structure of [Mo(η5-C9H7)(CO)2{P-η3-(tBu)CPC(tBu)PFBF3}]
In: Journal of organometallic chemistry, Jg. 466 (1994), Heft 1-2, S. 153-158
academicJournal
- print, 22 ref
Zugriff:
The phosphaalkyne tBuCP undergoes cyclodimerization at a molybdenum centre to afford a 1,3-diphosphacyclobutadiene complex in which, unusually, the four-membered ring is η3 ligated to the metal.
Titel: |
Synthesis and structural characterization of an unusual η3-ligated 1,3-diphosphacyclobutadiene molybdenum complex via cyclodimerization of a phosphaalkyne. Crystal structure of [Mo(η5-C9H7)(CO)2{P-η3-(tBu)CPC(tBu)PFBF3}]
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Autor/in / Beteiligte Person: | HITCHCOCK, P. B ; MOHD JAMIL, MAAH ; NIXON, J. F ; GREEN, M |
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Zeitschrift: | Journal of organometallic chemistry, Jg. 466 (1994), Heft 1-2, S. 153-158 |
Veröffentlichung: | Lausanne: Elsevier Science, 1994 |
Medientyp: | academicJournal |
Umfang: | print, 22 ref |
ISSN: | 0022-328X (print) |
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