Alkenylidazenido complexes of molybdenum and tungsten derived from dinitrogen complexes : their synthesis, characterization, and novel reactivities
In: Journal of the American Chemical Society, Jg. 114 (1992), Heft 25, S. 9890-9898
Online
academicJournal
- print, 28 ref
Zugriff:
α-Deprotonation of molybdenum or tungsten diazoalkane complexes trans-[MF(NN=CR1CHR2R3) (dpe)2] [BF4] (1, M=Mo or W, dpe=Ph2PCH2CH2PPh2) by LDA (lithium diisopropylamide) or NaN(SiMe3)2 provides a general route to alkenyldiazenido complexes trans-[MF(NNCR1=CR2R3) (dpe)2].
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Alkenylidazenido complexes of molybdenum and tungsten derived from dinitrogen complexes : their synthesis, characterization, and novel reactivities
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Autor/in / Beteiligte Person: | ISHII, Y ; MIYAGI, H ; JITSUKUNI, S ; SEINO, H ; HARKNESS, B. S ; HIDAI, M |
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Zeitschrift: | Journal of the American Chemical Society, Jg. 114 (1992), Heft 25, S. 9890-9898 |
Veröffentlichung: | Washington, DC: American Chemical Society, 1992 |
Medientyp: | academicJournal |
Umfang: | print, 28 ref |
ISSN: | 0002-7863 (print) |
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