Synthesis and spectroscopy of mono- and Di-nuclear copper complexes of a pyrazolylcyclotriphosphazene. crystal structure of an unusual cyclotriphosphazene-bridged dicopper complex
In: Journal of the Chemical Society. Dalton transactions, 1993, Heft 17, S. 2589-2594
Online
academicJournal
- print, 28 ref
Zugriff:
The mononuclear copper(II) complexes [CuL(ClO4) (H2O)2] ClO2, and [CuL(bipy)(ClO4)]ClO4, [L=2,2,4,4,6,6-hexakis(3.5-dimethylpyrazolyl)-2λ5,4λ5,6λ5-cyclotriphosphaza- 1,3.5-triene] have been prepared and characterized by optical, EPR and IR spectral data. The crystal structure of an unusual cyclophosphazene-bridged dicopper complex [H2dmpz] [(CuCl2)2{N3P3O(dmpz)5}] (Hdmpz=3.5dimethylpyrazole) has been determined: space group P1.
Titel: |
Synthesis and spectroscopy of mono- and Di-nuclear copper complexes of a pyrazolylcyclotriphosphazene. crystal structure of an unusual cyclotriphosphazene-bridged dicopper complex
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Autor/in / Beteiligte Person: | THOMAS, K. R. J ; VADAPALLI, CHANDRASEKHAR ; SCOTT, S. R ; HALLFORD, R ; CORDES, A. W |
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Zeitschrift: | Journal of the Chemical Society. Dalton transactions, 1993, Heft 17, S. 2589-2594 |
Veröffentlichung: | Cambridge: Royal Society of Chemistry, 1993 |
Medientyp: | academicJournal |
Umfang: | print, 28 ref |
ISSN: | 0300-9246 (print) |
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