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Three inorganic-organic hybrid compounds with the formula CuL(VO2)(PO4), L = 4,4'-bipy, 1,10-phen, and 2,2'-bipy, were hydrothermally synthesized at 160°C for 120 h and characterized by single-crystal X-ray diffraction. The use of different bidentate organodiamine ligands in initial reaction systems gave rise to the variety in the structures of the products: Cu(4,4'-bipy)(VO2)(PO4) (1) and Cu(1,10-phen)(VO2)(PO4) (2) crystallize in a monoclinic system with space group C2/c, a = 21.952(4) Å, b = 8.0805(13) Å, c = 15.918(2) Å, β = 110.689(4)°, and V = 2641.5(7) Å3, and a = 20.4557(12) Å, b = 11.6231(7) Å, c = 14.6422(8) Å, β = 127.5520(10)°, and V = 2760.0(3) Å3, respectively. Cu(2,2'-bipy)(VO2)(PO4) (3) crystallizes in a triclinic system with space group P1, a = 5.561(5) Å, b = 10.271(9) Å, c = 11.780(9) Å, a = 74.31(3)°, β = 79.98(3)°, γ = 85.74(3)°, and V = 637.6(9) Å3. The structures of 1 and 2 possess the same {(VO2)(PO4)}2 four-membered rings, whereas the structure of 3 contains {(VO2)(PO4)}∞ infinite chains. In terms of the organic parts, the {Cu(4,4'-bipy)}∞ linear chains connect the {(VO2)(PO4)}2 four-membered rings to build up a 3D framework in 1, whereas the Cu(1,10-phen)2+ and Cu(2,2'-bipy)2+ fragments link with the {(VO2)(PO4)}2 four-membered rings and {(VO2)(PO4)}∞ infinite chains to give two 1D structures of 2 and 3, respectively. Their thermal stabilities were investigated.

Titel:	Hydrothermal syntheses and X-ray crystal structures of three inorganic-organic hybrid materials in a copper vanadium phosphate family : CuL(VO2)(PO4) (L = 4,4'-bipy, 1,10-phen, 2,2'-bipy)
Autor/in / Beteiligte Person:	ZHAN, SHI ; SHOUHUA, FENG ; LIRONG, ZHANG ; GUOYU, YANG ; JIA, HUA
Link:	E-Journal im Bestand der UB Hagen? View record from PASCAL Archive
Zeitschrift:	Chemistry of materials, Jg. 12 (2000), Heft 10, S. 2930-2935
Veröffentlichung:	Washington, DC: American Chemical Society, 2000
Medientyp:	academicJournal
Umfang:	print, 40 ref
ISSN:	0897-4756 (print)
Schlagwort:	Chemistry Chimie Chemical industry parachemical industry Industrie chimique et parachimique Polymers, paint and wood industries Polymères, industries des peintures et bois Sciences exactes et technologie Exact sciences and technology Physique Physics Etat condense: structure, proprietes mecaniques et thermiques Condensed matter: structure, mechanical and thermal properties Structure des liquides et des solides; cristallographie Structure of solids and liquids; crystallography Structure de solides cristallins particuliers Structure of specific crystalline solids Composés minéraux Inorganic compounds Complexes métalliques Metal complexes Chimie generale et chimie physique General and physical chemistry Etat colloïdal et états dispersés Colloidal state and disperse state Matériaux poreux Porous materials Chimie minerale et origine de la vie Inorganic chemistry and origins of life Préparations et propriétés Preparations and properties Sels complexes Coordination compounds Composé minéral Inorganic compound Compuesto inorgánico Métal transition complexe Transition element complexes Chaîne Chain Cadena Complexe dinucléaire Dinuclear complex Complejo dinuclear Complexe hétéronucléaire Heteronuclear complex Complejo heteronuclear Complexe mu Mu complex Complejo mu Complexe phosphato Phosphato complex Complejo fosfato Composé aromatique Aromatic compound Compuesto aromático Composé tricyclique Tricyclic compound Compuesto tricíclico Coordinat organique Organic ligand Ligando orgánico Cuivre Vanadium Complexe Copper Vanadium Complexes Cobre Vanadio Complejo Cycle 6 chaînons Six membered ring Ciclo 6 eslabones Diffraction RX X ray diffraction Difracción RX Etude expérimentale Experimental study Estudio experimental Hétérocycle azote Nitrogen heterocycle Heterociclo nitrógeno Préparation chimique Chemical preparation Stabilité thermique Thermal stability Estabilidad térmica Structure cristalline Crystalline structure Estructura cristalina Structure moléculaire Molecular structure Estructura molecular Synthèse hydrothermale Hydrothermal synthesis 1,10-Phénanthroline 2,2p-Bipyridyle 4,4p-Bipyridyle Matériau hybride Hybrid material Structure ouverte Open framework
Sonstiges:	Nachgewiesen in: PASCAL Archive Sprachen: English Original Material: INIST-CNRS Document Type: Article File Description: text Language: English Author Affiliations: Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China Rights: Copyright 2001 INIST-CNRS ; CC BY 4.0 ; Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS Notes: General chemistry and physical chemistry ; Mineral chemistry and origin of life ; Physics of condensed state: structure, mechanical and thermal properties

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Hydrothermal syntheses and X-ray crystal structures of three inorganic-organic hybrid materials in a copper vanadium phosphate family : CuL(VO2)(PO4) (L = 4,4'-bipy, 1,10-phen, 2,2'-bipy)