Synthesis and characterization of copper(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)
In: Bulletin of Natural Sciences Research, Jg. 11 (2021), Heft 1, S. 24-28
Online
academicJournal
Zugriff:
The syntheses, physicochemical and structural properties of the novel Cu(II) complex with 2,6-diacetylpyridine bis(phenylhydrazone) (L), of the formula [CuL 2 ]Br 2 are presented. In the reaction of warm MeOH solutions of the ligand, 2,6-diacetylpyridine bis(phenylhydrazone) and CuBr 2 in molar ratio 2:1 resulted in formation of black single crystals of the bis(ligand) complex. This is the first Cu(II) complex with this ligand that is characterized by SC-XRD. Two ligand molecules are coordinated in the usual tridentate mode, via nitrogen atoms of the pyridine ring, and two azomethine nitrogen atoms, forming distorted octahedral environments of the metal ion.
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Synthesis and characterization of copper(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)
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Autor/in / Beteiligte Person: | Svetlana, Belošević ; Radanović Mirjana M. ; Rodić Marko V. ; Leovac Vukadin M. |
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Zeitschrift: | Bulletin of Natural Sciences Research, Jg. 11 (2021), Heft 1, S. 24-28 |
Veröffentlichung: | University of Priština - Faculty of Natural Sciences and Mathematics, Kosovska Mitrovica, 2021 |
Medientyp: | academicJournal |
ISSN: | 2738-1013 (print) |
DOI: | 10.5937/bnsr11-30567 |
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