Preparation, photo- and electrochemical studies of a homoleptic imine-phosphaalkene Cu(I) complex
2020
Online
Elektronische Ressource
A 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) functionalized phosphaalkene was used as a bidentate ligand towards a [Cu(I)L-2](+) complex. The spectroscopic, electrochemical and photophysical properties of the compound were studied revealing a rich redox chemistry indicative of ligand non-innocence. The compound is weakly emissive with excited state lifetimes of up to 9 ns. NMR and electrochemical analysis indicate a complex dynamic behavior of this photosensitizer in solution.
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Preparation, photo- and electrochemical studies of a homoleptic imine-phosphaalkene Cu(I) complex
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Veröffentlichung: | 2020 |
Medientyp: | Elektronische Ressource |
DOI: | 10.1016.j.ica.2020.119958 |
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