Selective benzylic carbon hydrogen bond activation of toluenes and aromatic carbon halogen bond activation of halobenzenes by rhodium(III) porphyrins.
2006
Online
Elektronische Ressource
by Chiu Peng Fai.
Thesis (M.Phil.)--Chinese University of Hong Kong, 2006.
Includes bibliographical references (leaves 82-87).
s in English and Chinese.
Table of Contents --- p.i
Acknowledgements --- p.iv
Abbreviations --- p.v
p.vi
Chapter Chapter 1 --- Introduction
Chapter 1.1 --- Definition of Carbon Hydrogen Bond Activation (CHA) by Transition Metal Comple --- p.1 x
Chapter 1.2 --- The Importance of Alkane CHA and its Potential Use --- p.1
Chapter 1.3 --- Difficulties in Alkane CHA --- p.3
Chapter 1.4 --- The Use of Transition Metal Complexes in CHA Reactions --- p.4
Chapter 1.5 --- Classification of CHA Reactions --- p.6
Chapter 1.6 --- The Importance of Toluene and Benzene CHA --- p.11
Chapter 1.7 --- Difficulties and Challenges in CHA of Toluene --- p.11
Chapter 1.8 --- Selectivity Control and Rate Promotion --- p.12
Chapter 1.9 --- Structural Features of Rhodium Porphyrins --- p.17
Chapter 1.10 --- CHA by Rhodium Porphyrins --- p.19
Chapter 1.11 --- Objective of Work --- p.21
Chapter Chapter 2 --- CHA Reactions of Toluenes by Rhodium Porphyrin Chlorides
Chapter 2.1 --- Synthesis of Rhodium Porphyrin Chlorides --- p.22
Chapter 2.2 --- Temperature Effects of CHA in Toluene --- p.22
Chapter 2.3 --- Inter and Intra Molecular Exchange of Alkyl Rhodium Porphyrin Complexes --- p.24
Chapter 2.4 --- Electronic Effect of Rhodium Porphyrin Chlorides --- p.24
Chapter 2.5 --- Electronic Effect of Toluene Towards CHA --- p.25
Chapter 2.6 --- X-Ray Data --- p.26
Chapter 2.7 --- Mechanistic Studies --- p.30
Chapter 2.8 --- Ligand and Base Effects --- p.32
Chapter 2.9 --- Optimization of Reaction Conditions --- p.35
Chapter 2.10 --- Electronic Effect of Toluenes --- p.36
Chapter 2.11 --- Concentraction Effects of Toluenes (Reactions in Benzene) --- p.38
Chapter 2.12 --- Porphyrin Effects in CHA of Toluene --- p.39
Chapter 2.13 --- Mechanistic Studies --- p.40
Chapter 2.14 --- Conclusion --- p.42
Chapter 2.15 --- Reaction between Rh(ttp)Me and Toluenes --- p.42
Chapter 2.16 --- Selective Benzylic CHA --- p.42
Chapter 2.17 --- Isotope Effect --- p.44
Chapter 2.18 --- Discussion --- p.44
Chapter 2.19 --- Exploratory Studies of Other Base-Promoted Reactions --- p.45
Chapter 2.20 --- Benzylic CHA and Aromatic Carbon Halogen Bond Activation (CXA) Reactions --- p.45
Chapter 2.21 --- Base-Enhanced Aromatic CXA --- p.48
Chapter 2.22 --- X-Ray Data --- p.49
Chapter 2.23 --- Base-Enhanced Benzylic Carbon Carbon Bond Activation (CCA) Reactions --- p.51
Chapter 2.24 --- Summary --- p.52
Chapter Chapter 3 --- Experimental Sections --- p.53
References --- p.82
Appendix I Crystal Data and Processing Parameters --- p.88
Appendix II List of Spectra --- p.123
Spectra --- p.125
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| Titel: |
Selective benzylic carbon hydrogen bond activation of toluenes and aromatic carbon halogen bond activation of halobenzenes by rhodium(III) porphyrins.
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| Veröffentlichung: | 2006 |
| Medientyp: | Elektronische Ressource |
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