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Low emissions, high working capacity adsorbent and canister system

Ingevity South Carolina, LLC
2023
Online Patent

Titel:
Low emissions, high working capacity adsorbent and canister system
Autor/in / Beteiligte Person: Ingevity South Carolina, LLC
Link:
Veröffentlichung: 2023
Medientyp: Patent
Sonstiges:
  • Nachgewiesen in: USPTO Patent Grants
  • Sprachen: English
  • Patent Number: 11565,239
  • Publication Date: January 31, 2023
  • Appl. No: 17/482206
  • Application Filed: September 22, 2021
  • Assignees: INGEVITY SOUTH CAROLINA, LLC (North Charleston, SC, US)
  • Claim: 1. A shaped adsorbent material comprising: an admixture of a binder and an activated adsorbent powder having a butane activity (pBACT) of at least about 50 g/100 g, derived by grinding an activated adsorbent precursor, wherein the admixture is shaped into a form, wherein the shaped adsorbent material has an ASTM BWC of at least 13 g/dL, and at least one of: (i) a ratio of pore volumes of 0.05-1 micron to 0.05-100 microns that is greater than about 80%, (ii) a ratio of pore volumes of 0.05-0.5 micron to 0.05-100 microns that is greater than about 50%, or (iii) a combination thereof.
  • Claim: 2. The shaped adsorbent material of claim 1 , wherein the activated adsorbent precursor is an activated carbon precursor.
  • Claim: 3. The shaped adsorbent material of claim 1 , wherein the binder comprises at least one of an organic binder, an inorganic binder or a combination thereof.
  • Claim: 4. The shaped adsorbent material of claim 3 , wherein the organic binder is at least one of carboxymethyl cellulose (CMC), a synthetic organic binder or a combination thereof.
  • Claim: 5. The shaped adsorbent material of claim 3 , wherein the inorganic binder is a clay.
  • Claim: 6. The shaped adsorbent material of claim 2 , wherein the activated carbon precursor is derived from at least one of wood, wood dust, wood flour, cotton linters, peat, coal, coconut, lignite, carbohydrates, petroleum pitch, petroleum coke, coal tar pitch, fruit pits, fruit stones, nut shells, nut pits, sawdust, palm, vegetables, a synthetic polymer, natural polymer, lignocellulosic material, or a combination thereof.
  • Claim: 7. The shaped adsorbent material of claim 1 , wherein the form is selected from a pellet, a granule, a sphere, a honeycomb, a monolith, a cylinder, a particulate, a hollow-cylinder, a star, a twisted spiral, a asterisk, a configured ribbon, or a combination thereof.
  • Claim: 8. A shaped adsorbent material comprising: an admixture of a binder and an activated adsorbent powder having a butane activity (pBACT) of at least about 50 g/100 g, derived by grinding an activated adsorbent precursor, wherein the admixture is shaped into a form, wherein the shaped adsorbent material has an ASTM BWC of at least 13 g/dL, and at least one of: (i) a ratio of pore volumes of 0.05-1 micron to 0.05-100 microns that is greater than about 80%, and (ii) a ratio of pore volumes of 0.05-0.5 micron to 0.05-100 microns that is greater than about 50%.
  • Claim: 9. The shaped adsorbent material of claim 8 , wherein the activated adsorbent precursor is an activated carbon precursor.
  • Claim: 10. The shaped adsorbent material of claim 8 , wherein the binder comprises at least one of an organic binder, an inorganic binder or a combination thereof.
  • Claim: 11. The shaped adsorbent material of claim 10 , wherein the organic binder is at least one of carboxymethyl cellulose (CMC), a synthetic organic binder or a combination thereof.
  • Claim: 12. The shaped adsorbent material of claim 10 , wherein the inorganic binder is a clay.
  • Claim: 13. The shaped adsorbent material of claim 9 , wherein the activated carbon precursor is derived from at least one of wood, wood dust, wood flour, cotton linters, peat, coal, coconut, lignite, carbohydrates, petroleum pitch, petroleum coke, coal tar pitch, fruit pits, fruit stones, nut shells, nut pits, sawdust, palm, vegetables, a synthetic polymer, natural polymer, lignocellulosic material, or a combination thereof.
  • Claim: 14. The shaped adsorbent material of claim 10 , wherein the form is selected from a pellet, a granule, a sphere, a honeycomb, a monolith, a cylinder, a particulate, a hollow-cylinder, a star, a twisted spiral, a asterisk, a configured ribbon, or a combination thereof.
  • Patent References Cited: 3864277 February 1975 Kovach ; 4169747 October 1979 De Rooy et al. ; 4677086 June 1987 McCue et al. ; 4894072 January 1990 Turner et al. ; 4999048 March 1991 Freepons ; 5039651 August 1991 Kosaka et al. ; 5162286 November 1992 MacDowall ; 5204310 April 1993 Tolles et al. ; 5250491 October 1993 Yan ; 5324703 June 1994 McCue et al. ; 5538932 July 1996 Yan et al. ; 5691270 November 1997 Miller ; 5863858 January 1999 Miller ; 5957114 September 1999 Johnson et al. ; 6098601 August 2000 Reddy ; 6277179 August 2001 Reymonet ; 6279548 August 2001 Reddy ; 6472343 October 2002 McCrae et al. ; 6540815 April 2003 Hiltzik et al. ; 6599856 July 2003 Uchino et al. ; RE38844 October 2005 Hiltzik ; 9174195 November 2015 Yamasaki et al. ; 9322368 April 2016 Arase et al. ; 9657691 May 2017 Eguchi et al. ; 9732649 August 2017 Hiltzik et al. ; 20050123763 June 2005 Hiltzik ; 20060154815 July 2006 Abe et al. ; 20080063592 March 2008 Nakahara et al. ; 20100212496 August 2010 Hanamoto ; 20130186375 July 2013 Hasegawa ; 20150184621 July 2015 Arase et al. ; 20150275727 October 2015 Hiltzik et al. ; 20160271555 September 2016 Hiltzik et al. ; 20180207611 July 2018 Byrne et al. ; 20190101083 April 2019 Hiltzik ; 102856081 January 2013
  • Other References: Burchell, “Carbon Material for Advanced Technologies,” 1999, pp. 252-253. cited by applicant ; CARB's LEV III BETP procedure (section D.12 in California Evaporative Emissions Standards and Test Procedures for 2001 and Subsequent Model Motor Vehicles, Mar. 22, 2012). cited by applicant ; International Preliminary Report on Patentability for PCT/US2018/053823, dated Mar. 31, 2020. cited by applicant ; International Search Report and Written Opinion for PCT/US2018/053823 dated Jan. 1, 2019. cited by applicant ; Itakura et al., “Studies on Carbon Canisters to Satisfy LEVII EVAP Regulations,” 2000. cited by applicant ; Johnson et al., “Performance Of Activated Carbon in Evaporative Loss Control Systems,” SAE Technical Papers 902119, 1990. cited by applicant ; Limits and Measurement Methods for Emissions from Light-Duty Vehicles, GB 18352.6-2016, also known as “China 6” 2016. cited by applicant ; Williams et al. “Impact and Control of Canister Bleed Emissions,” SAE Technical Paper, 2001. cited by applicant
  • Assistant Examiner: Gitman, Gabriel E
  • Primary Examiner: Miller, Jonathan
  • Attorney, Agent or Firm: Zerhusen, Esq., Bryan D. ; Herrel, Esq., Nicholas R. ; Cantor Colburn LLP

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