Interface-Engineered InAlN/Cu2O Photocathode with Accelerated Charge Separation for Boosting Photoelectrochemical Water Splitting
In: Solar RRL
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Zugriff:
Cu2O has emerged as a promising material for sustainable hydrogen production through photoelectrochemical (PEC) water splitting, while inefficient charge separation remains one of the main challenges hindering its development. In this work, a new architecture of InAlN/Cu2O heterojunction photocathode is demonstrated by combining n-type InAlN and p-type Cu2O to improve the charge separation efficiency, thus enhancing PEC water-splitting performance. The Pt/InAlN/Cu2O photoelectrode exhibits a photocurrent density of 2.54 mA cm−2 at 0 V versus reversible hydrogen electrode (VRHE), which is 3.21 times higher than that of Cu2O (0.79 mA cm−2 at VRHE). The enhanced PEC performance is explained by the larger built-in potential Vbi of 1.43 V formed at the InAlN/Cu2O p–n junction than that in the single Cu2O photocathode (Vbi < 0.77 V), which improves the separation of the photogenerated carriers and thus relieves the bottlenecks of charge-transfer kinetics at the electrode bulk and electrode/electrolyte interface. In this work, an avenue is opened for designing III-nitrides/Cu2O heterojunction toward solar energy conversion.
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Interface-Engineered InAlN/Cu2O Photocathode with Accelerated Charge Separation for Boosting Photoelectrochemical Water Splitting
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Autor/in / Beteiligte Person: | Zeng, Hui ; Chang, Jui Che ; Qu, Yuanju ; Wang, Weimin ; Birch, Jens ; Hsiao, Ching Lien ; Sun, Jianwu |
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Zeitschrift: | Solar RRL |
Medientyp: | unknown |
ISSN: | 2367-198X (print) |
DOI: | 10.1002/solr.202400094 |
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