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Benzil Schiff Base Side-Chain Polymer-Crosslinked Chitosan Via Hydrothermal Process for Reactive Orange 16 Dye Removal: An Optimized and Comparative Study with Chitosan.
In: Journal of Polymers & the Environment, Jg. 31 (2023-05-01), Heft 5, S. 1986-2004
Online
academicJournal
Zugriff:
Herein, a novel hydrothermally cross-linked chitosan-benzil (CTS-BZ) was prepared by a facile hydrothermal process. The physicochemical characteristics of the developed adsorbents were analyzed using CHN-O, BET, XRD, FTIR, pHpzc, and SEM analytical techniques. The characterization results demonstrated the mesoporous and crystal line nature of the CTS-BZ as well as the successful grafting of the aromatic ring of the BZ onto the CTS chains. The hydrothermally cross-linked CTS-BZ and chitosan (CTS) were employed for the removal of reactive orange 16 (RO16) dye in a comparative way. Response surface methodology (RSM) was adopted in collaboration with Box-Behnken design (BBD) to optimize the important parameters impacting RO16 adsorption, namely; adsorbent dose (A: 0.02–0.08 g), pH (B: 4–10), and time (C: 5–25). The Langmuir and Freundlich models accurately described the isotherm adsorption data of RO16 by CTS and RO16 by CTS-BZ, respectively. Kinetic adsorption results for RO16 by both CTS beads and CTS-BZ were well-described by the pseudo-second-order model. Remarkably, the hydrothermally cross-linked CTS-BZ revealed a maximum adsorption capacity for RO16 of 291.8 mg/g, as compared with the CTS's adsorption capacity of 227.5 mg/g. The adsorption of RO16 onto the hydrothermally cross-linked CTS-BZ surface is largely controlled by a variety of mechanisms including electrostatic forces, H-bonding, π-π stacking, and n-π interactions. This study shows that novel hydrothermally cross-linked CTS-BZ outperforms pristine CTS beads as a very effective adsorbent for the removal of hazardous contaminants from water. [ABSTRACT FROM AUTHOR]
Titel: |
Benzil Schiff Base Side-Chain Polymer-Crosslinked Chitosan Via Hydrothermal Process for Reactive Orange 16 Dye Removal: An Optimized and Comparative Study with Chitosan.
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Autor/in / Beteiligte Person: | Normi, Nurul Izzati ; Abdulhameed, Ahmed Saud ; Surip, S. N. ; ALOthman, Zeid A. ; Wilson, Lee D. ; Jawad, Ali H. |
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Zeitschrift: | Journal of Polymers & the Environment, Jg. 31 (2023-05-01), Heft 5, S. 1986-2004 |
Veröffentlichung: | 2023 |
Medientyp: | academicJournal |
ISSN: | 1566-2543 (print) |
DOI: | 10.1007/s10924-022-02727-4 |
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